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Ace's Monologue to Mel in the classic Doctor Who serial Dragonfire.
This scene shows Ace's depth as a Character which would be explored in future stories, in the subequent seasons following this story it also shows why she's a fan favorite character and one of the most beloved companions of the Doctor.
The Seventh Doctor is my favorite Doctor, the way Sylvester McCoy balanced out the lighter aspects of the character with a darker Machiavellian nature.
This portrayal of The Doctor is the one I find the most interesting, I also feel that it added another layer mystery to a character felt they thought they knew.